Carbonaceous components in particulate matter during a haze episode at a typical industrial area in the North China Plain

Abstract

Purpose

Severe airborne particulate pollution frequently occurs over the North China Plain (NCP) region in recent years. To better understand the characteristics of carbonaceous components in particulate matter (PM) over the NCP region.

Design/methodology/approach

PM samples were collected at a typical area affected by industrial emissions in Handan, in January 2016. The concentrations of organic carbon (OC) and elemental carbon (EC) in PM of different size ranges (i.e. PM_2.5, PM₁₀ and TSP) were measured. The concentrations of secondary organic carbon (SOC) were estimated by the EC tracer method.

Findings

The results show that the concentration of OC ranged from 14.9 μg m⁻³ to 108.4 μg m⁻³, and that of EC ranged from 4.0 μg m⁻³ to 19.4μg m⁻³, when PM_2.5 changed from 58.0μg m⁻³ to 251.1μg m⁻³ during haze days, and the carbonaceous aerosols most distributed in PM_2.5 rather than large fraction. The concentrations of OC and EC PM_2.5 correlated better (r = 0.7) than in PM_2.5−10 and PM_>10, implying that primary emissions were dominant sources of OC and EC in PM_2.5. The mean ratios of OC/EC in PM_2.5, PM_2.5–10 and PM_>10 were 4.4 ± 2.1, 3.6 ± 0.9 and 1.9 ± 0.7, respectively. Based on estimation, SOC accounted for 16.3%, 22.0% and 9.1% in PM_2.5, PM_2.5–10 and PM_>10 respectively.

Originality/value

The ratio of SOC/OC (48.2%) in PM_2.5 was higher in Handan than those (28%–32%) in other megacities, e.g. Beijing, Tianjin and Shijiazhuang in the NCP, suggesting that the formation of SOC contributed significantly to OC. The mean mass absorption efficiencies of EC (MACEC) in PM₁₀ and TSP were 3.4 m² g⁻¹ (1.9–6.6 m² g⁻¹) and 2.9 m² g⁻¹ (1.6–5.6 m² g⁻¹), respectively, both of which had similar variation patterns to those of OC/EC and SOC/OC.

Citation

Niu, H., Liu, Z., Hu, W., Cheng, W., Li, M., Xue, F., Wu, Z., Wang, J. and Fan, J. (2021), "Carbonaceous components in particulate matter during a haze episode at a typical industrial area in the North China Plain", World Journal of Engineering, Vol. 18 No. 2, pp. 293-301. https://doi.org/10.1108/WJE-05-2020-0157