Corrosion inhibition of aluminium in 0.3 M HCl using starch mucor in potassium iodide as inhibitor

Abstract

Purpose

The purpose of this study is to investigate starch mucor (SM) in potassium iodide (KI) as corrosion inhibitor of aluminium in hydrochloric acid (HCl) medium.

Design/methodology/approach

The SM in KI was characterized by gravimetric, scanning electron microscopy, electrochemical impedance spectroscopy measurements, potentiodynamic polarization and gas chromatography-mass spectrometer techniques. The inhibition efficiency was optimized using response surface methodology.

Findings

The result revealed that the inhibitor inhibited corrosion at a low concentration with the rate of inhibition increasing as the concentration of the inhibitor increased. The inhibition efficiency increases as the temperature was increased with slight incorporation of the inhibitor (SM in KI). This indicates that the corrosion control is both inhibitor (SM in KI) and temperature dependent.

Originality/value

The research results can provide the basis for using SM in KI as corrosion inhibitor of aluminium in HCL medium. Mixed-type inhibitor nature of SM was proved by cathodic and anodic nature of the polarization curves.

Citation

Ezeamaku, U.L., Eze, I., Odimegwu, N., Nwakaudu, A., Okafor, A., Onukwuli, O.D. and Nnanwube, I.A. (2023), "Corrosion inhibition of aluminium in 0.3 M HCl using starch mucor in potassium iodide as inhibitor", Pigment & Resin Technology, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/PRT-12-2022-0152