TY  - JOUR
AB  - Purpose– The mechanisms of the deblocking reaction of the polyurethane with blocking agent were investigated in detail relatively using thermogravimetric analysis (TGA), Fourier transform infrared spectrometry (FTIR) and X-ray photoelectron spectroscopy (XPS). This kind of method for polyurethane as the application of wood adhesives can provide the conditions of application and the main theoretical basis. Design/methodology/approach– The blocking rate and latex particle size distribution were determined using the titrimetric analysis and the laser particle analysis, respectively. TGA, FTIR, XPS and differential scanning calorimetry were used to investigate the deblocking temperature and time of the blocked isocyanate in detail. Findings– The results indicated that the blocking rate was approximately 97 per cent and the average particle size was 360 nm. The results of laser particle analysis have confirmed that the dispersivity of the blocked polyurethane emulsion was good. XPS results showed that the amount of –O = C-N-benzyl groups increased with an increasing deblocking temperature and subsequently reached equilibrium. In summary, the blocked isocyanate was deblocked at temperatures ranging from 50 to 90°C. Research limitations/implications– An important approach in future wood adhesive work would be to gain access to man-made board application data. Practical implications– The paper provided some useful information about deblocking mechanisms of blocked polyurethane that would be helpful to guide applied practical applications as wood adhesive. Social implications– To promote China’s wood processing technology progress and solve the problem of shortage of the natural quality of wood is of important practical significance. Originality/value– The paper is the first to use the XPS characterisation method to characterise deblocking polyurethane solution.
VL  - 43
IS  - 4
SN  - 0369-9420
DO  - 10.1108/PRT-08-2013-0074
UR  - https://doi.org/10.1108/PRT-08-2013-0074
AU  - Zhang Yanhua
AU  - Cao Jun
AU  - Tan Haiyan
AU  - Gu Jiyou
PY  - 2014
Y1  - 2014/01/01
TI  - New thermal deblocking characterisation method of aqueous blocked polyurethane
T2  - Pigment & Resin Technology
PB  - Emerald Group Publishing Limited
SP  - 194
EP  - 200
Y2  - 2024/09/19
ER  -