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Polyurethane resin derived from polyol of palm olein and recycled poly(ethylene terephthalate)

Abbas Ahmad Adamu (Department of Chemistry, University of Malaya, Kuala Lumpur, Malaysia)
Norazilawati Muhamad Sarih (Department of Chemistry, University of Malaya, Kuala Lumpur, Malaysia)
Seng Neon Gan (Department of Chemistry, University of Malaya, Kuala Lumpur, Malaysia)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 3 February 2021

Abstract

Purpose

Poly(ethylene terephthalate) (PET) waste from soft drink bottles was incorporated into palm olein alkyd to produce new polyol for use in polyurethane resins as surface protection on metal surfaces.

Design/methodology/approach

Alkyd was prepared from palm olein, glycerol and phthalic anhydride. PET underwent simultaneous glycolysis and transesterification reactions with the alkyd. Varying the amount of PET has led to polyols with different viscosities. Polyurethane resins were produced by reacting the polyols with toluene diisocyanate. The resins were coated on mild steel panels and cured. Performances of the cured films were tested.

Findings

The polyurethanes (PU) resin cured to a harder film with better thermal stability. Films showed excellent adhesion properties, while higher content of PET exhibited higher pencil hardness, better water, salt, acid and alkali resistance.

Research limitations/implications

Other vegetable oils could also be used. The alkyd structure could be changed by formulation to have different functionality and the ability to incorporate higher amount of PET waste. Rate of glycolysis of PET could be increased by higher amount of ethylene glycol.

Practical implications

This method has managed to use waste PET in producing new polyol and PU resins. The cured films exhibit good mechanical and chemical properties, as well as excellent adhesion and thermal stability.

Social implications

The non-biodegradable PET has created environmental pollution problems connected to littering and illegal landfilling. It has become necessary to pay greater attention to recycling PET bottles for obtaining valuable products.

Originality/value

This approach is different from the earlier reports, where PET was recycled to recover the raw materials.

Keywords

Acknowledgements

Conflicts of interest: There is no conflict of interest to declare.

The authors appreciate the University of Malaya for monetary funding (PG311-2016A) and Impact-Oriented Interdisciplinary Research Grant (IIRG006A-19IISS).

Citation

Adamu, A.A., Muhamad Sarih, N. and Gan, S.N. (2021), "Polyurethane resin derived from polyol of palm olein and recycled poly(ethylene terephthalate)", Pigment & Resin Technology, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/PRT-06-2020-0056

Publisher

:

Emerald Publishing Limited

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