Adsorptive removal of congo red dye from aqueous solutions using Mo-doped CoFe₂O₄ magnetic nanoparticles

Abstract

Purpose

The main purpose of this paper is to investigate the adsorption properties of CoFe_1.9Mo_0.1O₄ magnetic nanoparticles (CFMo MNPs) using, anionic dye “congo red (CR)” as a model of water pollutants.

Design/methodology/approach

The magnetic nano-adsorbent was synthesized via sol-gel process. Different techniques including; Fourier transform infrared spectroscopy, point of zero charge, scanning electron microscope and X-ray powder diffraction were used to characterize the prepared adsorbent. Adsorption experiments were conducted in batch mode under various conditions (contact time, shaking speed, initial dye concentration, initial solution pH, solution temperature and adsorbent amount) to investigate the adsorption capability of CFMo MNPs for CR.

Findings

The results showed that, CFMo MNPs could successfully remove more than 90% of CR dye within 20 min. Adsorption kinetics and isotherms were better described using pseudo-second-order (PSO) and Langmuir models, respectively. The maximum adsorbed amount (q_max) of CR dye was 135.14 mg/g. The adsorption process was found to be endothermic and spontaneous in nature as demonstrated by the thermodynamics ( ΔGo, ΔHoand ΔSo).

Practical implications

This study provided a good example of using an easily separated magnetic nano-adsorbent for fast removal of a very toxic organic pollutant, congo red, from the aquatic environment

Originality/value

The employment of Mo-doped cobalt ferrite for the first time for removing hazardous anionic dyes such as congo red from their aqueous solutions.

Citation

Amar, I.A., Asser, J.O., Mady, A.S., Abdulqadir, M.S., Altohami, F.A., Sharif, A.A. and Abdalsamed, I.A. (2021), "Adsorptive removal of congo red dye from aqueous solutions using Mo-doped CoFe₂O₄ magnetic nanoparticles", Pigment & Resin Technology, Vol. 50 No. 6, pp. 563-573. https://doi.org/10.1108/PRT-02-2020-0016