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Corrosion inhibition action of Landolphia heudelotii on mild steel in acidic media

Chinyere Elizabeth Agiriga (Department of Chemistry, Africa Centre of Excellence in Future Energies and Electrochemical Systems (ACE- FUELS), Federal University of Technology, Owerri, Nigeria)
Emeka Oguzie (Department of Chemistry, Africa Centre of Excellence in Future Energies and Electrochemical Systems (ACE- FUELS), Federal University of Technology, Owerri, Nigeria)
Arinzechukwu Chidiebere (Department of Science Laboratory Technology, Africa Centre of Excellence in Future Energies and Electrochemical Systems (ACE- FUELS), Federal University of Technology Owerri, Nigeria)
Nnaemeka John Okorocha (Department of Pure and Industrial Chemistry, University of Calabar, Calabar, Nigeria)
Reginald Ndubuisi Chikwe (Department of Chemistry, Federal University of Technology, Owerri, Nigeria)

Pigment & Resin Technology

ISSN: 0369-9420

Article publication date: 7 May 2020

Issue publication date: 28 August 2020

92

Abstract

Purpose

This paper aims to investigate the corrosion inhibition efficiency of Landolphia heudelotii (LH) on mild steel in 1 M HCl and 0.5 M H2SO4 using weight loss and potentiodynamic polarization techniques.

Design/methodology/approach

Water extract of LH was used as corrosion inhibitor on mild steel in acidic media at room temperature and elevated temperatures (30-60°C). Various concentrations of the plant extract were prepared from the stock solution obtained after solvent extraction. The inhibition efficiency of LH extract was evaluated and mechanism of adsorption was deduced.

Findings

LH extract showed significant corrosion inhibition on mild steel in both acidic media, with inhibition efficiency increasing with extract concentration. Potentiodynamic polarization measurements revealed mixed inhibition mechanism. Optimum inhibition efficiency was recorded at 2500 mg/L after 288 h. Mechanism of adsorption was mainly of physisorption. The inhibitor exhibited good inhibition efficiency even at elevated temperature.

Research limitations/implications

This study provides new data on the anticorrosion characteristics of LH extract under the specified conditions. Further studies could expand the experimental variables and use advanced surface probe techniques.

Practical implications

The developed inhibitor provides an alternative method of inhibiting corrosion on mild steel using eco-friendly materials from natural products which are less toxic, safer, cost-effective and readily available.

Originality/value

The method used was effective and the inhibitor developed can be incorporated in surface coatings where mild steel is used as construction materials, as tube sheets, rods and bars.

Keywords

Acknowledgements

The authors gratefully acknowledge the World Bank funded Africa Centers of Excellence for Development Impact (ACE Impact) Project.

Citation

Agiriga, C.E., Oguzie, E., Chidiebere, A., Okorocha, N.J. and Chikwe, R.N. (2020), "Corrosion inhibition action of Landolphia heudelotii on mild steel in acidic media", Pigment & Resin Technology, Vol. 49 No. 5, pp. 387-392. https://doi.org/10.1108/PRT-02-2019-0015

Publisher

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Emerald Publishing Limited

Copyright © 2020, Emerald Publishing Limited

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