Synergistic inhibition of aluminium corrosion in H₂SO₄ solution by polypropylene glycol in the presence of iodide ions

Abstract

Purpose

The purpose of this paper is to evaluate the performance of polypropylene glycol (PPG), as a corrosion inhibitor for aluminium corrosion in 0.5 M H₂SO₄ solution at 303-333 K and the effect of addition of iodide ions on the corrosion inhibition efficacy of PPG.

Design/methodology/approach

The corrosion inhibition performance of PPG alone and on addition of iodide ions in the acid medium was evaluated using weight loss and electrochemical [electrochemical impedance spectroscopy (EIS), linear polarisation resistance (LPR) and potentiodynamic polarization (PDP)] methods as well as surface analysis approach at 303-333 K. The morphology of the corroding aluminium surface without and with the additives was visualised using scanning electron microscopy (SEM). The trend of inhibition efficiency with temperature was used to propose the mechanism of inhibition and type of adsorption.

Findings

Results obtained showed that PPG moderately retarded the corrosion of Al in 0.5 M H₂SO₄ solution. Addition of KI to PPG is found to synergistically improve the inhibitive ability of PPG. From the variation of inhibition efficiency, K_ads, and E_a, with rise in temperature, physisorption mechanism is proposed for the adsorption of PPG and PPG + KI onto the Al surface in 0.5 M H₂SO₄ solution. Polarisation results showed that PPG and PPG + KI acted as mixed type inhibitor. The adsorption of PPG and PPG + KI, respectively, onto the metal surface followed El-Awady et al. adsorption isotherm model. SEM and water contact angle analysis confirmed the adsorption of PPG and PPG + KI on Al surface.

Research limitations/implications

The research is limited to aqueous acid environment in aerated condition, and all tests were performed under static conditions.

Practical implications

The use of PPG as corrosion inhibitor for Al corrosion in acidic medium were reported for the first time. The results suggest that iodide ions could be used to enhance corrosion protection ability of PPG which could find practical application in corrosion control in aqueous acidic environment. The data obtained would form part of database on the synergistic effect of iodide ions addition to polymer to control acid-induced corrosion of metal.

Originality/value

The use of PPG as corrosion inhibitor for Al corrosion in acidic medium were reported for the first time. The results suggest that iodide ions could be used to enhance corrosion protection ability of PPG which could find practical application in corrosion control in aqueous acidic environment. The data obtained would form part of database on the synergistic effect of iodide ions addition to polymer to control acid-induced corrosion of metal.

Citation

Solomon, M.M., Umoren, S.A., Israel, A.U. and Etim, I.G. (2016), "Synergistic inhibition of aluminium corrosion in H₂SO₄ solution by polypropylene glycol in the presence of iodide ions", Pigment & Resin Technology, Vol. 45 No. 4, pp. 280-293. https://doi.org/10.1108/PRT-01-2015-0010