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1,2,4,5 tetrazo spiro (5,4) decane‐3 thione as a corrosion inhibitor for arsenical aluminium brass in 3.5% NaCl solution

L. John Berchmans (Central Electrochemical Research Institute, Karaikudi, India)
S. Venkatakrishna Iyer (Central Electrochemical Research Institute, Karaikudi, India)
V. Sivan (Department of Metallurgical Engineering, Regional Engineering College, Tiruchirappalli, India)
M.A. Quraishi (Department of Applied Chemistry Z.H. College of Engineering and Technology, Aligarh Muslim University, Aligarh (UP), India)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 1 December 2001

1231

Abstract

The influence of a newly synthesised organic compound on the inhibition of corrosion of arsenical aluminium brass in a NaCl solution has been investigated using weight loss measurements, potentiodynamic polarization studies and impedance measurements. Different corrosion kinetic parameters obtained from polarisation studies reveal that the inhibition of corrosion of arsenical aluminium brass in NaCl is under mixed control. UV‐reflectance, X‐ray diffraction and scanning electron microscopic studies have also been carried out to understand the mechanism of inhibition of corrosion, and also the morphological changes on the surface of the alloy. The adsorption of this compound on the metal surface from 3.5% NaCl solution is found to obey Temkin’s adsorption isotherm.

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Citation

Berchmans, L.J., Venkatakrishna Iyer, S., Sivan, V. and Quraishi, M.A. (2001), "1,2,4,5 tetrazo spiro (5,4) decane‐3 thione as a corrosion inhibitor for arsenical aluminium brass in 3.5% NaCl solution", Anti-Corrosion Methods and Materials, Vol. 48 No. 6, pp. 376-381. https://doi.org/10.1108/EUM0000000006259

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MCB UP Ltd

Copyright © 2001, MCB UP Limited

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