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Zwitterionic molecule layer for inhibiting microbial corrosion of copper alloy

Fengling Xu (State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao, China)
Zhenghui Qiu (State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao, China)
Ri Qiu (State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao, China and Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, China)
Jiadong Yang (State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao, China)
Cunguo Lin (State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao, China)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 2 January 2018

170

Abstract

Purpose

For mitigating biocorrosion induced by sulfate-reducing bacteria (SRB) in seawater, the zwitterionic molecule layer (ZML) of poly (sulfobetaine methacrylate) is grafted onto B10 surface by chemical vapor deposition and surface-initiated atom transfer radical polymerization.

Design/methodology/approach

Energy-dispersive spectroscopy-attenuated total reflectance Fourier transform infrared spectroscopy and static contact angle measurements are used to characterize the as-formed layer.

Findings

After surface modification, B10 can significantly reduce SRB adhesion, demonstrating the good antifouling property. Further, the biocorrosion inhibition is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy, indicating that ZML exhibits high resistance to biocorrosion with inhibition efficiency of approximately 90 per cent.

Originality/value

ZML performs a dual feature, i.e. antifouling film and corrosion inhibitor, for the biocorrosion inhibition.

Keywords

Acknowledgements

This work was supported by Foundation of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences (MCKF201605) and 973 Program (2014CB643305).

Citation

Xu, F., Qiu, Z., Qiu, R., Yang, J. and Lin, C. (2018), "Zwitterionic molecule layer for inhibiting microbial corrosion of copper alloy", Anti-Corrosion Methods and Materials, Vol. 65 No. 1, pp. 46-52. https://doi.org/10.1108/ACMM-12-2016-1744

Publisher

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Emerald Publishing Limited

Copyright © 2018, Emerald Publishing Limited

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