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Preparation and characterization of a cerium conversion film on magnesium alloy

Jie Sun (School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang, China.)
Gang Wang (School of Environmental and Chemical Engineering, Shenyang Ligong University, Shenyang, China.)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 1 June 2015

269

Abstract

Purpose

The purpose of this paper was to prepare the cerium-based conversion coating on AZ91D magnesium alloy, and its compositions, micro-morphology, corrosion resistance and the chemical valence state of the film elements were investigated.

Design/methodology/approach

The methodology comprised preparation of coatings at different temperatures, which then were characterized using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy, an electrochemistry workstation and by means of X-ray photoelectron spectroscopy.

Findings

The conversion coating had a micro-cracked morphology. The conversion coatings were composed of MgO (or Mg-OH), CeO2 and Ce2O3. The best corrosion resistance of the cerium passivation film appeared when the treatment temperature was about 35°C.

Originality/value

The corrosion current densities of conversion coatings were lower by one to two orders of magnitude than the corrosion current density of the blank sample. The rare earth passivation coating prepared under the best condition could reduce the corrosion current to 3.548 × 10−6 A/cm2.

Keywords

Citation

Sun, J. and Wang, G. (2015), "Preparation and characterization of a cerium conversion film on magnesium alloy", Anti-Corrosion Methods and Materials, Vol. 62 No. 4, pp. 253-258. https://doi.org/10.1108/ACMM-12-2013-1336

Publisher

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Emerald Group Publishing Limited

Copyright © 2015, Emerald Group Publishing Limited

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