Appraisal on corrosion performances of CrNi, TiAlN/CrNi and CrNi–Al₂O₃–TiO₂ coatings on H13 hot work mold

Abstract

Purpose

The purpose of this paper is to evaluate the salt spray corrosion (SSC) and electrochemical corrosion performances of CrNi, TiAlN/NiCr and CrNi–Al₂O₃–TiO₂ coatings on H13 steel, which improved the corrosion resistance of H13 hot work mold.

Design/methodology/approach

CrNi, TiAlN/NiCr and CrNi–Al₂O₃–TiO₂ coatings were fabricated on H13 hot work mold steel using a laser cladding and cathodic arc ion plating. The SSC and electrochemical performances of obtained coatings were investigated using a corrosion test chamber and electrochemical workstation, respectively. The corrosion morphologies, microstructure and phases were analyzed using an electron scanning microscope, optical microscope and X-ray diffraction, respectively, and the mechanisms of corrosion resistance were also discussed.

Findings

The CrNi coating is penetrated by corrosion media, producing the oxide of Fe₃O₄ on the coating surface; and the TiAlN coating is corroded to enter into the CrNi coating, forming the oxides of TiO and NiO, the mechanism is pitting corrosion, whereas the CrNi–Al₂O₃–TiO₂ coating is not penetrated, with no oxides, showing the highest SSC resistance among the three kinds of coatings. The corrosion potential of CrNi coating, TiAlN/CrNi and CrNi–Al₂O₃–TiO₂ coatings was –0.444, –0.481 and –0.334 V, respectively, and the corresponding polarization resistances were 3,074, 2,425 and 86,648 cm², respectively. The electrochemical corrosion resistance of CrNi–Al₂O₃–TiO₂ coating is the highest, which is enhanced by the additions of Al₂O₃ and TiO₂.

Originality/value

The CrNi, TiAlN/CrNi and CrNi–Al₂O₃–TiO₂ coatings on H13 hot work mold were firstly evaluated by the SSC and electrochemical performances.

Citation

Dejun, K. and Jiahong, L. (2020), "Appraisal on corrosion performances of CrNi, TiAlN/CrNi and CrNi–Al₂O₃–TiO₂ coatings on H13 hot work mold", Anti-Corrosion Methods and Materials, Vol. 67 No. 2, pp. 150-157. https://doi.org/10.1108/ACMM-09-2019-2175