A Mannich base 1-phenyl-3-(1-pyrrolidinyl)-1-propanone: synthesis and performance study on corrosion inhibition for N80 steel in 15% hydrochloric acid

Abstract

Purpose

The purpose of this paper is to set out a study of a Mannich base, which was synthesized and used as an acidizing corrosion inhibitor first, and to the corrosion inhibitor mechanism.

Design/methodology/approach

A Mannich base, 1-phenyl-3-(1-pyrrolidinyl)-propanone (PHPP), was synthesized with acetophenone, pyrrolidine and formaldehyde at pH = approximately 2-3. The structure of PHPP was characterized by elemental analysis and Fourier transform infrared spectroscopy (FTIR). The corrosion inhibition of PHPP on N80 steel in 15 per cent hydrochloric acid (HCl) was studied by weight loss method, scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDAX), and the adsorption behavior of PHPP on the surface of N80 steel was discussed.

Findings

The results showed that the inhibition efficiency reached to 99.8 per cent and corrosion rate was 2.65 g·m-2·h-1 at 0.6 per cent of PHPP concentration in 15 per cent HCl, which indicated that PHPP presented excellent corrosion inhibition performance. The results of SEM and EDAX analysis showed that PHPP could be absorbed on the surface of N80 steel. The adsorption process of PHPP on the surface of N80 steel was chemisorption. This process was spontaneous and obeyed Langmuir adsorption isotherm.

Originality/value

It was found that PHPP presented excellent corrosion inhibition performance, and it is practicable to enhance oil production in oilfield development as a oil-well acidizing inhibitor. The study results can provide theoretical guidelines for the development of the inhibitor.

Citation

Pan, Y., Zhan, F., Lu, Z., Lin, Y., Yang, Z. and Wang, Z. (2016), "A Mannich base 1-phenyl-3-(1-pyrrolidinyl)-1-propanone: synthesis and performance study on corrosion inhibition for N80 steel in 15% hydrochloric acid", Anti-Corrosion Methods and Materials, Vol. 63 No. 2, pp. 153-159. https://doi.org/10.1108/ACMM-08-2013-1298