Alkaline corrosion properties of laser-clad aluminum/titanium coatings

Martin Aggerbeck (Department of Mechanical Engineering, Materials and Surface Engineering, Technical University of Denmark, Kgs. Lyngby, Denmark)
Alexis Herbreteau (Department of Mechanical Engineering, Materials and Surface Engineering, Technical University of Denmark, Kgs. Lyngby, Denmark)
Marleen Rombouts (VITO – Laser Centre Flanders, MOL, Belgium)
Jo Verwimp (VITO – Laser Centre Flanders, MOL, Belgium)
Rajan Ambat (Department of Mechanical Engineering, Materials and Surface Engineering, Technical University of Denmark, Kgs. Lyngby, Denmark)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Publication date: 5 January 2015

Abstract

Purpose

The purpose of this paper is to study the use of titanium as a protecting element for aluminum in alkaline conditions.

Design/methodology/approach

Aluminum coatings containing up to 20 weight per cent Ti6Al4V were produced using laser cladding and were investigated using light optical microscope, scanning electron microscope – energy-dispersive X-ray spectroscopy and X-Ray Diffraction, together with alkaline exposure tests and potentiodynamic measurements at pH 13.5.

Findings

Cladding resulted in a heterogeneous solidification microstructure containing an aluminum matrix with supersaturated titanium (<1 weight per cent), Al3Ti intermetallics and large partially undissolved Ti6Al4V particles. Heat treatment lowered the titanium concentration in the aluminum matrix, changed the shape of the Al3Ti precipitates and increased the degree of dissolution of the Ti6Al4V particles. Corrosion testing showed significant localized dissolution of the aluminum matrix.

Research limitations/implications

Increased titanium concentration and heat treatment gave improved alkaline corrosion properties. At pH 13.5, the Al3Ti phases were protected, while the aluminum matrix corroded.

Practical implications

For alkaline corrosion-protection of aluminum in the automobile industry, titanium might be useful at pH values below 13.5 or by using other coating techniques.

Originality/value

This is the first study testing the use of titanium as a protective element of aluminum in stringent alkaline conditions.

Keywords

Acknowledgements

The authors thank the Danish Agency for Science, Technology and Innovation for their financial support of the IdeAl project. Thanks to all partners in the IDEAL innovation consortium. Thanks to all employees at DTU MEK, Materials and Surface Engineering who have helped with experiments.

Citation

Aggerbeck, M., Herbreteau, A., Rombouts, M., Verwimp, J. and Ambat, R. (2015), "Alkaline corrosion properties of laser-clad aluminum/titanium coatings", Anti-Corrosion Methods and Materials, Vol. 62 No. 1, pp. 37-47. https://doi.org/10.1108/ACMM-07-2013-1290

Publisher

:

Emerald Group Publishing Limited

Copyright © 2015, Emerald Group Publishing Limited

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