Fabrication of modified graphite bipolar plates by indirect selective laser sintering (SLS) for direct methanol fuel cells

Abstract

Purpose

The purpose of this paper is to produce electrically conductive, fluid impermeable graphite bipolar plates for a direct methanol fuel cell, using indirect selective laser sintering (SLS) and suitable post processing techniques.

Design/methodology/approach

Bipolar plates are made by the indirect SLS of graphite powder and phenolic resin mixture. The phenolic resin binder is then burnt off at a high temperature in a vacuum furnace to produce a 100 per cent carbon part. This brown part is then infiltrated using a low‐viscosity (∼5‐10  cps) cyanoacrylate to seal up the open pores, rendering the plates fluid impermeable.

Findings

It has been found that the electrical conductivity increases significantly (> 220 S/cm) with a corresponding increase in pyrolyzing temperature which correlates well with literature on the carbonization of phenol formaldehyde resins. The cyanoacrylate infiltrated parts tested under fluid pressure demonstrated no leakage through the plate, indicating full closure of open porosity.

Originality/value

This work demonstrates the capability of the SLS process to produce working bipolar plates with complex flow field designs that can be tested to verify its efficacy in a working fuel cell, thereby saving time and cost in machining natural graphite.

Citation

Alayavalli, K. and Bourell, D.L. (2010), "Fabrication of modified graphite bipolar plates by indirect selective laser sintering (SLS) for direct methanol fuel cells", Rapid Prototyping Journal, Vol. 16 No. 4, pp. 268-274. https://doi.org/10.1108/13552541011049289