Corrosion inhibition and adsorption properties of ethanol extract of Gongronema latifolium on mild steel in H2SO4

N.O. Eddy (Physical Chemistry Unit, Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria)
E.E. Ebenso (Department of Chemistry, North West University (Mafikeng Campus), Mmabatho, South Africa)

Pigment & Resin Technology

ISSN: 0369-9420

Publication date: 23 March 2010

Abstract

Purpose

The purpose of this paper is to study the inhibitive and adsorptive characteristics of ethanol extract of Gongronema latifolium (GL) as a corrosion inhibitor for mild steel in H2SO4.

Design/methodology/approach

The inhibition efficiencies were evaluated using thermometric and hydrogen evolution techniques.

Findings

The inhibition efficiency of ethanol extract of GL vary with concentration of the extract, period of immersion and with temperature. The extract acts as an inhibitor because of its phytochemical and amino acid composition. The extract is adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherm. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of some kinetic and thermodynamic parameters obtained.

Research limitations/implications

The study provides information on the use of ethanol extract of GL as a corrosion inhibitor. Electrochemical studies such as polarisation and alternating current impedance spectra will throw more light on the mechanistic aspects of the corrosion inhibition.

Practical implications

Ethanol extract of GL can be used as an environmentally friendly inhibitor for the corrosion of mild steel in H2SO4.

Originality/value

This environmentally friendly inhibitor could find possible applications in metal surface anodising and surface coatings.

Keywords

Citation

Eddy, N. and Ebenso, E. (2010), "Corrosion inhibition and adsorption properties of ethanol extract of Gongronema latifolium on mild steel in H2SO4", Pigment & Resin Technology, Vol. 39 No. 2, pp. 77-83. https://doi.org/10.1108/03699421011028653

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Publisher

:

Emerald Group Publishing Limited

Copyright © 2010, Emerald Group Publishing Limited

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