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New bipyrazole derivatives as effective inhibitors for the corrosion of mild steel in 1M HCI medium

A. El Ouafi (Laboratoire de Chimie des Eaux et Corrosion, Faculté des Sciences, Oujda, Morocco)
B. Hammouti (Laboratoire de Chimie des Eaux et Corrosion, Faculté des Sciences, Oujda, Morocco)
H. Oudda (Laboratoire de Chimie des Eaux et Corrosion, Faculté des Sciences, Oujda, Morocco)
S. Kertit (Laboratoire de Physico‐Chimie des Matériaux associated with l’AUPELF UREF (LAF 509), Ecole Normale Supérieure de Takaddoum, B.P. 5118. Rabat, Morocco)
R. Touzani (Laboratoire de Chimie Organique Physique (LCOP), Faculté des Sciences, Oujda, Morocco)
A. Ramdani (Laboratoire de Chimie Organique Physique (LCOP), Faculté des Sciences, Oujda, Morocco)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 1 June 2002

Abstract

The inhibition of the corrosion of the mild steel in 1M HCl by new bipyrazolic compounds has been studied by weight loss, electrochemical polarisation and electrochemical impedance spectroscopy (EIS) measurements. Results obtained reveal that these compounds are very good inhibitors. The inhibition efficiency increases with the increase of inhibitor concentration and reached 94 at 10–3M for the bipyrazoles studied. Potentiodynamic polarisation studies clearly reveal that the presence of the bipyrazoles does not change the mechanism of the hydrogen evolution reaction and they act essentially as cathodic inhibitors. The effect of temperature on the corrosion behaviour of mild steel in 1M HCl without and with the bipyrazoles at 10–3M was studied in the temperature range from 298° to 343°K. EIS measurements show the increase of the transfer resistance with the inhibitor concentration.

Keywords

Citation

El Ouafi, A., Hammouti, B., Oudda, H., Kertit, S., Touzani, R. and Ramdani, A. (2002), "New bipyrazole derivatives as effective inhibitors for the corrosion of mild steel in 1M HCI medium", Anti-Corrosion Methods and Materials, Vol. 49 No. 3, pp. 199-204. https://doi.org/10.1108/00035590210426463

Publisher

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MCB UP Ltd

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